Synthesis of hydrosilanes via Lewis-base-catalysed reduction of alkoxy silanes with NaBH4

Author:

Aoyagi Keiya12345,Ohmori Yu6745,Inomata Koya6745ORCID,Matsumoto Kazuhiro6745ORCID,Shimada Shigeru6745ORCID,Sato Kazuhiko6745,Nakajima Yumiko12345ORCID

Affiliation:

1. Department of Chemistry

2. Faculty of Pure and Applied Sciences

3. University of Tsukuba

4. Tsukuba

5. Japan

6. Interdisciplinary Research Center for Catalytic Chemistry

7. National Institute of Advanced Industrial Science and Technology (AIST)

Abstract

Hydrosilanes were synthesized by reduction of alkoxysilanes with BH3 in the presence of hexamethylphosphoric triamide (HMPA) as a Lewis-base catalyst. The reaction was also achieved using an inexpensive and easy-to-handle handled hydride source NaBH4, which reacted with EtBr as a sacrificial reagent to form BH3in situ.

Funder

New Energy and Industrial Technology Development Organization

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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