Crystal structure design and multiband physical properties of quaternary sulfide Ba5Bi2Co2S10 for optoelectronic conversion

Author:

Bu Kejun12345,Zhang Xian6785ORCID,Huang Jian12345,Luo Mengjia12345,Zheng Chong9101112,Wang Ruiqi131415165,Wang Dong12345,He Jianqiao12345,Zhao Wei12345,Che Xiangli12345,Huang Fuqiang12345ORCID

Affiliation:

1. State Key Laboratory of High Performance Ceramics and Superfine Microstructure

2. Shanghai Institute of Ceramics

3. Chinese Academy of Sciences

4. Shanghai 200050

5. P. R. China

6. Qian Xuesen Laboratory of Space Technology

7. China Academy of Space Technology

8. Beijing 100094

9. Department of Chemistry and Biochemistry

10. Northern Illinois University

11. DeKalb

12. USA

13. State Key Laboratory of Rare Earth Materials Chemistry and Applications

14. College of Chemistry and Molecular Engineering

15. Peking University

16. Beijing 100871

Abstract

Band alignment of hypothetical Bi–MT–S compounds with MT in Oh and Td symmetry, respectively. Crystal structure of Ba5Bi2Co2S10 viewed down the a-axis and multiband properties with optimal bandgap of Ba5Bi2Co2S10.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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