Revealing the evolution of local structures in the formation process of alkaline earth metal cation-containing zeolites from glasses

Author:

Hu Peidong12,Deguchi Makiko2,Yamada Hiroki234,Kobayashi Kentaro4ORCID,Ohara Koji34,Sukenaga Sohei5,Ando Mariko6,Shibata Hiroyuki5,Machida Akihiko7,Yanaba Yutaka8,Liu Zhendong12ORCID,Okubo Tatsuya2ORCID,Wakihara Toru12ORCID

Affiliation:

1. Institute of Engineering Innovation, The University of Tokyo, 2-11-16 Yayoi, Bunkyo-ku, Tokyo 113-8656, Japan

2. Department of Chemical System Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

3. Japan Synchrotron Radiation Research Institute/SPring-8, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198, Japan

4. Faculty of Materials for Energy, Shimane University, 1060 Nishi-Kawatsu-cho, Matsue, Shimane 690-8504, Japan

5. Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan

6. Graduate School of Engineering, Tohoku University, 6-6-04 Aramaki, Aoba-ku, Sendai 980-8579, Japan

7. Synchrotron Radiation Research Center, National Institutes for Quantum Science and Technology (QST), 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5148, Japan

8. Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505, Japan

Abstract

Pure harmotome was synthesized from a Ba-containing aluminosilicate glass. The structure-regulating role of Ba2+ and the transformation scheme were revealed by combining high-energy X-ray total scattering and anomalous X-ray scattering techniques.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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