‘Phoenix polymers’: fire induced nanohardness in fibril-forming aromatic cyanate esters

Author:

Mooring Lyndsey123,Thompson Scott123,Hall Stephen A.123,Pani Silvia45623,Zioupos Peter7893,Swan Martin10113,Stone Corinne10113,Howlin Brendan J.123ORCID,Hamerton Ian1213141516ORCID

Affiliation:

1. Department of Chemistry

2. Surrey

3. UK

4. Department of Physics

5. Faculty of Engineering and Physical Sciences

6. University of Surrey

7. Cranfield Forensic Institute

8. CDS

9. Cranfield University

10. Dstl

11. Salisbury

12. Bristol Composites Institute (ACCIS)

13. Department of Aerospace Engineering

14. School of Civil, Aerospace, and Mechanical Engineering

15. Queen's Building

16. University of Bristol

Abstract

For the first time we present nanoindentation analysis of charred, cured aromatic cyanate esters, which exhibit outstanding mechanical properties when analysed under applied loads of 0.1–300 mN.

Funder

Defence Science and Technology Laboratory

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference32 articles.

1. R. E.Lyon , Fire Resistant Materials: Research Overview DOT/FAA/AR-97/99 , FAA , 1997

2. Special Study: U.S. Air Carrier Accidents Involving Fire, 1965-1974 and Factors Affecting the Statistics, Report NTSB-AAS-77-1 , National Transportation Safety Board , February 17, 1977

3. Recent developments in the chemistry of halogen-free flame retardant polymers

4. G. J.Van Esch , Environmental health criteria 218—flame retardants: tris(2-butoxyethyl)phosphate, tris(2-ethylhexyl)-phosphate and tetrakis-(hydroxymethyl)phosphonium salts , WHO , Geneva , 2000

5. U.S. Environmental Protection Agency , EPA/600 , US GPO , Washington , 1994 , vol. 1–3

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