Cu4MnGe2S7 and Cu2MnGeS4: two polar thiogermanates exhibiting second harmonic generation in the infrared and structures derived from hexagonal diamond

Author:

Glenn Jennifer R.1,Cho Jeong Bin2,Wang Yiqun3,Craig Andrew J.1ORCID,Zhang Jian-Han4ORCID,Cribbs Marvene1,Stoyko Stanislav S.1,Rosello Kate E.1,Barton Christopher1,Bonnoni Allyson1,Grima-Gallardo Pedro56,MacNeil Joseph H.7,Rondinelli James M.3ORCID,Jang Joon I.2ORCID,Aitken Jennifer A.1ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, Duquesne University, Pittsburgh, PA 15282, USA

2. Department of Physics, Sogang University, Seoul, 04017, South Korea

3. Department of Materials Science and Engineering, Northwestern University, Evanston, IL, 60208-3108, USA

4. School of Resources and Chemical Engineering, Sangming University, Sanming, 365004, P.R. China

5. Centro de Estudios de Semiconductores, Departamento de Físcia, Facultad de Ciencias, Universidad de Los Andes, Mérida, 5101, Venezuela

6. Centro Nacional de Tecnologías Ópticas (CNTO), Mérida, 5101, Venezeula

7. Department of Chemistry, Chatham University, Pittsburgh, PA 15232, USA

Abstract

The synthesis, structure, and physicochemical characterization of two diamond-like semiconductors are reported. Both compounds display second harmonic generation, bandgaps around 2 eV and wide windows of optical transparency in the infrared.

Funder

Division of Chemistry

National Research Foundation of Korea

Division of Materials Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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