Enantioselective Peroxidation of <i>C</i>-alkynyl imines enabled by chiral BINOL calcium phosphate-Reference-Cited by-同舟云学术

Enantioselective Peroxidation of C-alkynyl imines enabled by chiral BINOL calcium phosphate

Published:2022 Issue:18 Volume:58 Page:3035-3038
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Sun Zhongwen¹²^ORCID,Chen Lijun¹,Qiu Kaixiong¹,Liu Bo¹,Li Hongtao¹,Yu Fang¹

Affiliation:

1. School of Pharmaceutical Science & Yunnan Key Laboratory of Pharmacology for Natural Products, Kunming Medical University, Kunming, 650500, China

2. Key Laboratory of State Forestry and Grassland Administration on Highly-Efficient Utilization of Forestry Biomass Resources in Southwest China, Southwest Forestry University, Kunming, 650224, China

Abstract

In a reaction catalyzed by a chiral calcium phosphate, hydroperoxides and in situ generated alkynyl imines afford C-alkynyl α-amino peroxides in generally excellent yields and high enantioselectivities.

Funder

Kunming Medical University

Yunnan Provincial Science and Technology Department

Southwest Forestry University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D1CC07156D

Reference43 articles.

1. Rearrangements of organic peroxides and related processes

2. Past and current routes to β-hydroperoxy alcohols: A functional group with high potential in organic synthesis

3. Natural Peroxy Anticancer Agents

4. Bioactive peroxides as potential therapeutic agents

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