Crystallisation temperature control of stoichiometry and selectivity in host–guest compounds
Author:
Affiliation:
1. Centre for Supramolecular Chemistry Research
2. Department of Chemistry
3. University of Cape Town
4. Rondebosch 7701
5. South Africa
6. Institut für Organische Chemie
7. TU Bergakademie Freiberg
8. D-09596 Freiberg/Sachs
9. Germany
Abstract
A bulky diol host is only selective for tertiary butanol when versus 2-propanol at low temperatures.
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/CE/C7CE01414G
Reference16 articles.
1. G. R. Desiraju , J. J.Vittal and A.Ramanan , Crystal Engineering , Imperial College Pres , London , 2012
2. F. Cramer , The Lock and Key principle , ed. J.-P. Behr , Wiley , Chichester , 1994 , ch. 1
3. E. V. Anslyn and D. A.Dougherty , Modern Physical Organic Chemistry , University Science Books , California , 2006 , ch 3
4. Temperature-controlled selectivity of isomeric guest inclusion: enclathration and release of xylenes by 1,1′-binaphthyl-2,2′-dicarboxylic acid
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