Direct intramolecular carbon(sp2)–nitrogen(sp2) reductive elimination from gold(iii)
Author:
Affiliation:
1. Department of Chemistry
2. University of Kentucky
3. Lexington
4. USA
5. Microbiology
6. Bioorganic & Macromolecular Chemistry
7. Faculty of Pharmacy
8. Université Libre de Bruxelles
9. Belgium
Abstract
The reactivity of bidentate AuIII–Cl species, [(C^N)AuCl2], with a bisphosphine or carbon donor ligands results in reductive elimination.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT05155K
Reference53 articles.
1. Gold Catalysis
2. R. H. Crabtree , in The Organometallic Chemistry of the Transition Metals , Wiley , Hoboken, NJ , 4th edn, 2005
3. An associative mechanism for reductive elimination of d8 NiR2(PR3)2
4. Reductive Elimination of d8-Organotransition Metal Complexes
5. Halide-Dependent Mechanisms of Reductive Elimination from Gold(III)
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