Formal insertion of selenoketenes into donor–acceptor cyclopropanes: mesomeric alkynylselenolates as key starting materials-Reference-Cited by-同舟云学术

Formal insertion of selenoketenes into donor–acceptor cyclopropanes: mesomeric alkynylselenolates as key starting materials

Published:2022 Issue:24 Volume:9 Page:6933-6939
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Jacob Anu¹,Jones Peter G.²,Werz Daniel B.³^ORCID

Affiliation:

1. Technische Universität Braunschweig, Institute of Organic Chemistry, Hagenring 30, 38106 Braunschweig, Germany

2. Technische Universität Braunschweig, Institute of Inorganic and Analytical Chemistry, Hagenring 30, 38106 Braunschweig, Germany

3. Albert-Ludwigs-Universität Freiburg, Institute of Organic Chemistry, Albertstraße 21, 79104 Freiburg, Germany

Abstract

The mesomerism of deprotonated selenoketene to deprotonated alkynylselenol is exploited to formally insert a selenoketene into donor–acceptor cyclopropanes.

Funder

Deutscher Akademischer Austauschdienst

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D2QO01568D

Reference72 articles.

1. Donor−Acceptor-Substituted Cyclopropane Derivatives and Their Application in Organic Synthesis

2. Application of oxygen/nitrogen substituted donor-acceptor cyclopropanes in the total synthesis of natural products

3. Heterocycles from cyclopropanes: applications in natural product synthesis

4. Donor‐Acceptor Cyclopropanes in the Synthesis of Carbocycles

5. Ring strain in cyclopropane, cyclopropene, silacyclopropane, and silacyclopropene

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