The synthesis and structure–property relation analysis of metal chalcohalide crystals Cs2InPS4X2 (X = Cl, Br) with mixed anions

Author:

Tang Chunlan12,Xing Wenhao2,Wang Naizheng34ORCID,Tang Jian2ORCID,Lin Zheshuai34ORCID,Wu Jieyun1ORCID,Yin Wenlong25ORCID,Kang Bin25

Affiliation:

1. School of Optoelectronic Science and Engineering, University of Electronic Science and Technology of China, Chengdu 611731, P.R. China

2. Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang 621900, P.R. China

3. University of Chinese Academy of Sciences, Beijing 100190, P. R. China

4. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

5. Key Laboratory of Science and Technology on High Energy Laser, China Academy of Engineering Physics, Mianyang 621900, P. R. China

Abstract

Two novel metal chalcogenides Cs2InPS4X2 (X = Cl, Br) were successfully synthesized and exhibit large optical band gaps induced by the [InS4X2]7− mixed-anion groups.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

China Academy of Engineering Physics

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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