Pentacoordinate silicon(iv): cationic, anionic and neutral complexes derived from the reaction of NHC→SiCl4 with highly Lewis acidic (C2F5)2SiH2-Reference-Cited by-同舟云学术

Pentacoordinate silicon(iv): cationic, anionic and neutral complexes derived from the reaction of NHC→SiCl4 with highly Lewis acidic (C2F5)2SiH2

Published:2014 Issue:47 Volume:50 Page:6204-6206
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Böttcher T.¹²³⁴,Steinhauer S.¹²³⁴,Neumann B.¹²³⁴,Stammler H.-G.¹²³⁴,Röschenthaler G.-V.⁵⁶⁷,Hoge B.¹²³⁴

Affiliation:

1. Universität Bielefeld

2. Centrum für Molekulare Materialien

3. Anorganische Chemie II

4. 33615 Bielefeld, Germany

5. Jacobs University Bremen

6. School of Engineering and Science

7. 28759 Bremen, Germany

Abstract

Addition of NHC→SiCl₄ to the highly Lewis acidic bis(pentafluoroethyl)silane ((C₂F₅)₂SiH₂) afforded the salt [(NHC)₂SiCl₂H][(C₂F₅)₂SiCl₃] with pentacoordinate silicon in the cation and the anion.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC02583K

Reference25 articles.

1. R. J. P. Corriu and J. C.Young , The Silicon-Heteroatom Bond (Chapter 1: Hypervalent Silicon Compounds) , Wiley , Chichester, England , 1989

2. Reactivity of penta- and hexacoordinate silicon compounds and their role as reaction intermediates

3. Comparison of Phosphorus and Silicon: Hypervalency, Stereochemistry, and Reactivity

4. Coordination complexes of silicon and germanium halides with neutral ligands

5. Adducts formed between some halogenosilanes and the organic bases pyridine, trimethylamine, and tetramethylethylenediamine. Part I. Stoichiometry

Cited by 20 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Neutral and Cationic Complexes of Silicon(IV) Halides with Phosphine Ligands;Inorganic Chemistry;2022-10-12

2. N ‐Heterocyclic Carbene and Cyclic (Alkyl)(amino)carbene Adducts of Germanium(IV) and Tin(IV) Chlorides and Organyl Chlorides;European Journal of Inorganic Chemistry;2022-08-18

3. An NHC‐Stabilized H 2 GeBH 2 Precursor for the Preparation of Cationic Group 13/14/15 Hydride Chains;Chemistry – A European Journal;2021-11-24

4. Investigating Tetrel-Based Neutral Frustrated Lewis Pairs for Hydrogen Activation;Inorganic Chemistry;2021-09-30

5. Molecular Main Group Metal Hydrides;Chemical Reviews;2021-08-27