Viologen–cucurbituril host/guest chemistry – redox control of dimerization versus inclusion

Author:

Dalvand Parastoo1,Nchimi Nono Katia2,Shetty Dinesh3ORCID,Benyettou Farah4,Asfari Zouhair5,Platas-Iglesias Carlos6ORCID,Olson Mark A.7ORCID,Trabolsi Ali4ORCID,Elhabiri Mourad1ORCID

Affiliation:

1. Université de Strasbourg, Université de Haute-Alsace, CNRS, LIMA, UMR 7042, Equipe Chimie Bioorganique et Médicinale, ECPM, 25 Rue Becquerel, 67000 Strasbourg, France

2. Department of Inorganic Chemistry, Faculty of Science, University of Yaoundé 1, Yaoundé, Cameroon

3. Department of Chemistry & Center for Catalysis and Separation (CeCaS), Khalifa University, Abu Dhabi, United Arab Emirates

4. New York University Abu Dhabi (NYUAD), Experimental Research Building, Building C1, Saadiyat Island, Abu Dhabi, United Arab Emirates

5. Equipe de Synthèse Pour l'Analyse (SynPA), Institut Pluridisciplinaire Hubert Curien (IPHC), UMR 7178 CNRS/Université de Strasbourg, ECPM, Bâtiment R1N0, 25-rue Becquerel, 67087 Strasbourg Cedex 2, France

6. Universidade da Coruña, Centro de Investigacións Científicas Avanzadas (CICA), Departamento de Química, Facultade de Ciencias, 15071 A Coruña, Galicia, Spain

7. Northwestern University, Department of Chemistry, 2145 Sheridan Rd, Evanston, Illinois, USA

Abstract

Two calix[4]arenes with two viologen units separated by 3 or 4 carbon atoms from the macrocyclic core were synthesized and led to the formation of [3]pseudorotaxanes when combined with CB[7] or CB[8].

Funder

Université de Strasbourg

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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