HUSY zeolite-promoted reactions of trifluoromethylated propargyl alcohols with arenes: synthesis of CF3-indenes and DFT study of intermediate carbocations

Author:

Nursahedova Selbi K.1234,Zerov Aleksey V.56734,Boyarskaya Irina A.56734,Grinenko Elena V.1234,Nenajdenko Valentine G.1894ORCID,Vasilyev Aleksander V.12345ORCID

Affiliation:

1. Department of Chemistry

2. Saint Petersburg State Forest Technical University

3. Saint Petersburg

4. Russia

5. Department of Organic Chemistry

6. Institute of Chemistry

7. Saint Petersburg State University

8. Lomonosov Moscow State University

9. Moscow

Abstract

Reaction of CF3-propargyl alcohols with arenes under the action of HUSY zeolite CBV-720 at 100 °C for 1 h affords CF3-indenes.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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