Light-mediated aerobic oxidation of C(sp<sup>3</sup>)–H bonds by a Ce(<scp>iv</scp>) hexachloride complex-Reference-Cited by-同舟云学术

Light-mediated aerobic oxidation of C(sp³)–H bonds by a Ce(iv) hexachloride complex

Published:2022 Issue:10 Volume:9 Page:2612-2620
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Wang Yu-Heng¹^ORCID,Yang Qiaomu¹^ORCID,Walsh Patrick J.¹^ORCID,Schelter Eric J.¹^ORCID

Affiliation:

1. P. Roy and Diana T. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA

Abstract

A photochemical C(sp3)–H oxygenation of arene and alkane substrates (including methane) catalyzed by [NEt4]2[CeIVCl6] under mild conditions (1 atm, 25 °C) is described.

Funder

Vagelos Institute for Energy Science and Technology, University of Pennsylvania, University of Pennsylvania

U.S. Department of Energy

National Science Foundation

NIH Clinical Center

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D2QO00362G

Reference78 articles.

1. Sustainability in Catalytic Oxidation: An Alternative Approach or a Structural Evolution?

2. Selective Oxidation Catalysis: Opportunities and Challenges

3. Catalytic selective oxidation: The forefront in the challenge for a more sustainable chemical industry

4. P. D.Ray and R. C.Fry , in Systems Biology in Toxicology and Environmental Health , ed. R. C. Fry , Academic Press , Boston , 2015 , pp. 11–42 . 10.1016/B978-0-12-801564-3.00002-X

5. Innovation of Hydrocarbon Oxidation with Molecular Oxygen and Related Reactions

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