Where do the counterions go? Tip-induced dissociation of self-assembled triazatriangulenium-based molecules on Au(111)-Reference-Cited by-同舟云学术

Where do the counterions go? Tip-induced dissociation of self-assembled triazatriangulenium-based molecules on Au(111)

Published:2021 Issue:16 Volume:23 Page:9930-9937
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Snegir S.¹²³⁴^ORCID,Dappe Y. J.⁵⁶⁷⁸⁹,Sysoiev D.¹⁰²³⁴,Pluchery O.¹¹⁷¹²¹³¹⁴^ORCID,Huhn T.¹⁰²³⁴^ORCID,Scheer E.¹²³⁴^ORCID

Affiliation:

1. Department of Physics

2. University of Konstanz

3. 78464 Konstanz

4. Germany

5. SPEC

6. CEA

7. CNRS

8. Université Paris-Saclay

9. CEA Saclay

10. Department of Chemistry

11. Sorbonne Université

12. Institut des NanoSciences de Paris (INSP)

13. 75005 Paris

14. France

Abstract

The interaction of the Au(111) surface with the molecules that have ionic bonds can lead to dissociation of the latter. This effect can be reinforced by the electric field of the STM tip, which requires the use of delicate STM tunneling parameters to visualize both the parent ion and its counterion.

Funder

Deutsche Forschungsgemeinschaft

Ministère des Affaires Étrangères

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP00221J

Reference33 articles.

1. Self-Assembled Monolayers of Thiolates on Metals as a Form of Nanotechnology

2. Molecular Self-Assembly at Solid Surfaces