Revisiting Ag–π interactions with bis((pyrrol-2-yl)methylene)hydrazine: CC versus CN bond complexation-Reference-Cited by-同舟云学术

Revisiting Ag–π interactions with bis((pyrrol-2-yl)methylene)hydrazine: CC versus CN bond complexation

Published:2019 Issue:12 Volume:21 Page:1853-1856
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Baudron Stéphane A.¹²³⁴⁵^ORCID,Chevreau Hubert⁶⁷⁸⁹

Affiliation:

1. Laboratoire de Tectonique Moléculaire

2. UMR CNRS 7140

3. icFRC

4. Université de Strasbourg

5. Strasbourg

6. Synchrotron SOLEIL

7. L'Orme des Merisiers

8. F-91192 Saint-Aubin

9. France

Abstract

Crystallographic and theoretical investigations of the assembly of bis((pyrrol-2-yl)methylene)hydrazine with Ag(i) salts suggest that, in the solid state, Ag–π interactions involve CC rather than CN pyrrolic bonds, in contrast with an earlier and unique report with this ligand.

Funder

Université de Strasbourg

LabEx Chimie des Systèmes Complexes

Ministère de l'Enseignement Supérieur et de la Recherche

Centre National de la Recherche Scientifique

Centre International de Recherche aux Frontières de la Chimie

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CE/C9CE00168A