The MMCT excited state of a localized mixed valence cyanido-bridged RuII–RuIII,III2

The MMCT excited state of a localized mixed valence cyanido-bridged RuII–RuIII,III2–RuII complex

Published:2019 Issue:25 Volume:48 Page:9303-9309
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Su Shao-Dong¹²³⁴⁵,Zhu Xiao-Quan¹²³⁴⁵,Zhang Lin-Tao¹²³⁴⁵,Yang Yu-Ying¹²³⁴⁵,Wen Yue-Hong¹²³⁴⁵,Wu Xin-Tao¹²³⁴⁵,Yang Song-Qiu⁶⁷³⁸⁵^ORCID,Sheng Tian-Lu¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Structural Chemistry

2. Fujian Institute of Research on the Structure of Matter

3. Chinese Academy of Sciences

4. Fuzhou 350002

5. China

6. State Key Laboratory of Molecular Reaction Dynamics

7. Dalian Institute of Chemical Physics

8. Dalian 116023

Abstract

The MMCT rate or the lifetime of the MMCT excited state could be controlled by a slight change of the substituent group on the metal center and was confirmed by the TA spectra.

Funder

National Natural Science Foundation of China

National Basic Research Program of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01503E

Reference39 articles.

1. V. Balzani , F.Bolletta , M. T.Gandolfi and M.Maestri , Organic Chemistry and Theory , Springer , Berlin and Heidelberg, Germany , 1978 , vol. 75 , pp. 1–64