Enantiodivergent reduction of α-keto amides catalyzed by high valent, chiral oxido-vanadium(v) complexes-Reference-Cited by-同舟云学术

Enantiodivergent reduction of α-keto amides catalyzed by high valent, chiral oxido-vanadium(v) complexes

Published:2020 Issue:17 Volume:7 Page:2505-2510
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Agarwal Rachit¹²³⁴^ORCID,Liao Yiya¹²³⁴,Lin Dai-Jen¹²³⁴,Yang Zhen-Xing¹²³⁴,Lai Chien-Fu¹²³⁴,Chen Chien-Tien¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. National Tsing Hua University

3. Hsinchu 30013

4. Taiwan

Abstract

Complementary asymmetric reductions of N-benzyl-α-keto amides were achieved for the first time by an air and moisture stable, reduced form of vanadyl(v) N-salicylidene-t-leucinate with HBPin and HBCat with up to 99% and 90% ee, respectively.

Funder

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/QO/C9QO01304K

Reference42 articles.

1. Synthesis, structure and applications of [cis-dioxomolybdenum(VI)-(ONO)] type complexes

2. Mononuclear Organomolybdenum(VI) Dioxo Complexes: Synthesis, Reactivity, and Catalytic Applications

3. Oxorhenium(V) Complexes with Phenolate–Pyrazole Ligands for Olefin Epoxidation Using Hydrogen Peroxide

4. Activation of Metal Oxo and Nitrido Complexes by Lewis Acids

Cited by 12 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Oxidation and Reduction;Organic Reaction Mechanisms Series;2024-03-15

2. Chemo- and Enantioselective Reduction of α-Keto Amides to α-Hydroxy Amides using Reusable CuO-Nanoparticles as Catalyst;The Journal of Organic Chemistry;2023-03-08

3. Copper-Catalyzed Transamidation of Unactivated Secondary Amides via C–H and C–N Bond Simultaneous Activations;The Journal of Organic Chemistry;2023-01-26

4. Enantioselective Meerwein–Ponndorf–Verley reduction of β,γ-unsaturated α-keto esters by asymmetric binary-acid catalysis in the green solvent iPrOH;Green Chemistry;2023

5. One-Pot Synthesis of α-Ketoamides from α-Keto Acids and Amines Using Ynamides as Coupling Reagents;The Journal of Organic Chemistry;2022-01-14