Abrupt spin crossover in iron(iii) complexes with aromatic anions-Reference-Cited by-同舟云学术

Abrupt spin crossover in iron(iii) complexes with aromatic anions

Published:2019 Issue:41 Volume:48 Page:15515-15520
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Lazaro Sharon E.¹²³⁴,Alkaş Adil⁵⁶⁷⁸,Lee Seok J.⁵⁶⁷⁸,Telfer Shane G.⁵⁶⁷⁸^ORCID,Murray Keith S.⁹¹⁰¹¹¹²^ORCID,Phonsri Wasinee⁹¹⁰¹¹¹²^ORCID,Harding Phimphaka¹²³⁴^ORCID,Harding David J.¹²³⁴^ORCID

Affiliation:

1. Functional Materials and Nanotechnology Center of Excellence

2. Walailak University

3. Thasala

4. Thailand

5. MacDiarmid Institute for Advanced Materials and Nanotechnology

6. Institute of Fundamental Sciences

7. Massey University

8. New Zealand

9. School of Chemistry

10. Monash University

11. Melbourne

12. Australia

Abstract

Two iron(iii) complexes, [Fe(qsal-X)₂]OTs·nH₂O, are found to exhibit abrupt spin crossover with the spin transition temperature substituent dependent, and X⋯O halogen bonds linking the spin centres.

Funder

Thailand Research Fund

Walailak University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02373A

Reference48 articles.

1. Spin-Crossover Materials: Properties and Applications , ed. M. A. Halcrow , John Wiley & Sons, Ltd , Chichester , 2013

2. Spin Crossover—An Overall Perspective