A theoretical study on the second-order nonlinear optical properties of Pt(ii) bis-acetylide complexes: substituent and redox effects

Author:

Sun Liting1,Wang Yingying1,Zhao Yuanyuan1ORCID,Qiu Yongqing1ORCID

Affiliation:

1. Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, China

Abstract

The introduction of a single –NO2 group in acetylide ligands increases the βtot of a complex 12 times, while one electron loss in five complexes enhances the βtot 496 times at the most.

Funder

National Natural Science Foundation of China

Doctoral Start-up Foundation of Liaoning Province

Publisher

Royal Society of Chemistry (RSC)

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