Na2B11H13 and Na11(B11H14)3(B11H13)4 as potential solid-state electrolytes for Na-ion batteries-Reference-Cited by-同舟云学术

Na₂B₁₁H₁₃ and Na₁₁(B₁₁H₁₄)₃(B₁₁H₁₃)₄ as potential solid-state electrolytes for Na-ion batteries

Published:2022 Issue:36 Volume:51 Page:13848-13857
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Souza Diego H. P.¹^ORCID,D'Angelo Anita M.²^ORCID,Humphries Terry D.¹^ORCID,Buckley Craig E.¹^ORCID,Paskevicius Mark¹^ORCID

Affiliation:

1. Department of Physics and Astronomy, Curtin University, GPO Box U1987, Perth, WA 6845, Australia

2. Australian Synchrotron (ANSTO), Clayton, VIC 3168, Australia

Abstract

Na2B11H13 and Na11(B11H14)3(B11H13)4 exhibit ionic conductivity above 1 mS cm−1 at 100 °C and an electrochemical stability of 2.1 V vs. Na+/Na. Na11(B11H14)3(B11H13)4 partially stabilises the high temeprature polymorph at 25 °C, which enhances Na+ conductivity.

Funder

Curtin University of Technology

Australian Research Council

Department of Industry and Science, Australian Government

Australian Synchrotron

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01943D

Reference74 articles.