Asymmetric syntheses of epohelmins A and B by In-mediated allylation

Author:

Liu Yi-Wen12345,Han Pan6375,Zhou Wen12345,Mao Zhuo-Ya12345,Si Chang-Mei12345,Wei Bang-Guo12345

Affiliation:

1. Department of Natural Products Chemistry

2. School of Pharmacy

3. Fudan University

4. Shanghai

5. China

6. Institutes of Biomedical Sciences

7. Shanghai, 200032

Abstract

Natural products epohelmins A and B have been asymmetrically synthesized by In-mediated allylation of α-chiral aldimine with allyl bromide.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference82 articles.

1. G. B. Fodor and B.Colasanti, The Pyridine and Piperidine Alkaloids: Chemistry and Pharmacology, in Alkaloids, Chemical and Biological Perspectives, ed. S. W. Pelletier, Wiley-Interscience, New York, NY, 1985, vol. 3, pp. 1–90

2. M. J. Schneider , Pyridine and Piperidine Alkaloids: An Update, in Alkaloids: Chemical and Biological Perspectives, ed. S. W. Pelletier, Pergamon, Oxford, UK, 1996, vol. 10, pp. 155–299

3. Asymmetric Synthesis of Hydroxylated Pyrrolidines, Piperidines and Related Bioactive Compounds: From N-Acyliminium Chemistry to N-α-Carbanion Chemistry

4. Recent Developments in the Synthesis of Pyrrolidine‐Containing Iminosugars

5. Asymmetric Synthesis via Acetal Templates. 14.1 Preparation of Enantiomerically Pure (3S,4S)- and (3S,4R)-Statine Derivatives

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