Unusual linkage photoisomerization in [Co(NH3)2NO2]2I3Cl single crystals-Reference-Cited by-同舟云学术

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Unusual linkage photoisomerization in [Co(NH₃)₂NO₂]₂I₃Cl single crystals

Published:2024 Issue: Volume: Page:
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Kalinina Polina P.¹^ORCID,Zakharov Boris A.¹^ORCID

Affiliation:

1. Novosibirsk State University, Pirogova 2, Novosibirsk 630090, Russian Federation

Abstract

The reaction [Co(NH3)5NO2]2+ → [Co(NH3)5ONO]2+ proceeds under visible light for cations in certain crystallographic positions only in [Co(NH3)5NO2]2I3Cl, that suggests “crystallographic control” of reactivity within the same crystal structure.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CE/D4CE00734D

Reference57 articles.

1. E. V.Boldyreva and V. V.Boldyrev , Reactivity of Molecular Solids , Wiley , Chester , 1999 , vol. 3 , pp. 1–50 and references therein

2. Mechanically Responsive Molecular Crystals

3. Intramolecular Linkage Isomerization in the Crystals of Some Co(III) - Ammine Complexes - A Link Between Inorganic and Organic Solid State Chemistry

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