Access to α,β-unsaturated carboxylic acids through water-soluble palladium catalyzed hydroxycarbonylation of alkynes using water as the solvent-Reference-Cited by-同舟云学术

Access to α,β-unsaturated carboxylic acids through water-soluble palladium catalyzed hydroxycarbonylation of alkynes using water as the solvent

Published:2021 Issue:14 Volume:11 Page:4708-4713
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Lv Jinhe¹²³⁴⁵,Zong Lingbo¹²³⁴⁵,Zhang Jinrong¹²³⁴⁵,Song Jiaxin¹²³⁴⁵,Zhao Jinyu¹²³⁴⁵,Zhang Kai¹²³⁴⁵,Zhou Ziqin¹²³⁴⁵,Gao Mingjie⁶⁷⁸⁹⁵,Xie Congxia¹²³⁴⁵^ORCID,Jia Xiaofei¹²³⁴⁵^ORCID,Ren Xinyi¹⁰¹¹¹²¹³⁵

Affiliation:

1. Shandong Key Laboratory of Biochemical Analysis

2. College of Chemistry and Molecular Engineering

3. Qingdao University of Science and Technology

4. Qingdao 266042

5. P. R. China

6. State Key Laboratory of Organometallic Chemistry

7. Shanghai Institute of Organic Chemistry

8. Chinese Academy of Sciences

9. Shanghai 200032

10. Shanghai Key Laboratory of Green Chemistry and Chemical Process

11. School of Chemistry and Molecular Engineering

12. East China Normal University

13. Shanghai 200241

Abstract

A reusable water-soluble Pd(OAc)₂/sulfoxantphos catalyst has been developed for the hydroxycarbonylation of symmetrical and unsymmetrical alkynes with CO/H₂O to afford the corresponding α,β-unsaturated carboxylic acids in good yields.

Funder

National Natural Science Foundation of China

Qingdao University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CY/D1CY00699A

Reference41 articles.

1. Hydrocarboxylation of alkynes utilizing CO2 as C1 synthon: A facile and environmentally benign access to α,β-unsaturated carboxylic acids

2. Efficient aerobic photooxygenation of aldehydes to carboxylic acids using cobalt(II) phthalocyanine sulfonate as a photosensitizer in organic-water biphasic media