Carbon monoxide-driven osmium catalyzed reductive amination harvesting WGSR power

Author:

Biriukov Klim O.123,Vinogradov Mikhail M.123ORCID,Afanasyev Oleg I.123ORCID,Vasilyev Dmitry V.4567ORCID,Tsygankov Alexey A.123,Godovikova Maria123,Nelyubina Yulia V.123,Loginov Dmitry A.12389,Chusov Denis12389ORCID

Affiliation:

1. A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences (INEOS RAS)

2. Moscow

3. Russian Federation

4. Forschungszentrum Jülich GmbH

5. Helmholtz Institute Erlangen-Nürnberg for Renewable Energy (IEK-11)

6. 91058 Erlangen

7. Germany

8. G. V. Plekhanov Russian University of Economics

9. Moscow 117997

Abstract

First osmium-catalyzed reductive amination under the water gas–shift reaction conditions was developed. Proposed catalytic system demonstrates high performance even at the catalyst loading as low as 0.0625 mol%.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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