Fe-BPsalan complex catalyzed highly enantioselective Diels–Alder reaction of alkylidene β-ketoesters-Reference-Cited by-同舟云学术

Fe-BPsalan complex catalyzed highly enantioselective Diels–Alder reaction of alkylidene β-ketoesters

Published:2021 Issue:9 Volume:8 Page:1910-1917
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Ping Yuan-Ji¹²³⁴,Zhou Yi-Ming¹²³⁴⁵,Wu Liang-Liang⁶⁷⁸⁹⁴^ORCID,Li Zong-Rui¹²³⁴,Gu Xin¹²³⁴,Wan Xiao-Long¹²³⁴,Xu Zhen-Jiang¹²³⁴,Che Chi-Ming¹²³⁴⁶^ORCID

Affiliation:

1. Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis

2. Shanghai Institute of Organic Chemistry

3. Shanghai 200032

4. China

5. The Education Ministry Key Lab of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials

6. State Key Laboratory of Synthetic Chemistry

7. Department of Chemistry

8. The University of Hong Kong

9. Hong Kong SAR

Abstract

A practical Fe-BPsalan-catalyzed asymmetric Diels–Alder reaction of various alkylidene β-ketoesters and dienes was developed to afford estrone analogues in excellent yields, good to high diastereoselectivities and excellent enantioselectivities.

Funder

National Natural Science Foundation of China

Shenzhen Fundamental Research Program

CAS-Croucher Funding Scheme for Joint Laboratories

Fujian Institute of Innovation, Chinese Academy of Sciences

Innovation and Technology Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D1QO00158B

Reference73 articles.

1. A. Patti , Green Approaches To Asymmetric Catalytic Synthesis , Springer , Heidelberg , 2011

2. E. N. Jacobsen , A.Pfaltz and H.Yamamoto , Comprehensive Asymmetric Catalysis , Springer , New York , 1999

3. I. Ojima , Catalytic Asymmetric Synthesis , John Wiley & Sons , New York , 3rd edn, 2010

4. Iron-catalysed carbon–heteroatom and heteroatom–heteroatom bond forming processes

5. Direct C−H Transformation via Iron Catalysis

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