Relationship between spatially heterogeneous reaction dynamics and photochemical kinetics in single crystals of anthracene derivatives

Author:

Kataoka Sogo1,Kitagawa Daichi1ORCID,Sotome Hikaru2ORCID,Ito Syoji2ORCID,Miyasaka Hiroshi2ORCID,Bardeen Christopher J.3ORCID,Kobatake Seiya1ORCID

Affiliation:

1. Department of Chemistry and Bioengineering, Graduate School of Engineering, Osaka Metropolitan University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka, 558-8585, Japan

2. Division of Frontier Materials Science and Center for Promotion of Advanced Interdisciplinary Research, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama-cho, Toyonaka, Osaka 560-8531, Japan

3. Department of Chemistry, University of California, Riverside, 501 Big Springs Road, Riverside, CA 92521, USA

Abstract

Both the photochemical kinetics and the spatial reaction dynamics in single crystals could be rationalized in terms of the difference in the cooperativity of the reactions that relates the magnitude of the conformational change required for reaction.

Funder

National Science Foundation

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

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