Polyoxovanadate catalysts for oxidation of 1-phenyl ethanol: from the discrete [V4O12]4− and [V10O28]6− anions to the anionic [V6O17]n4n− coordination polymer-Reference-Cited by-同舟云学术

Polyoxovanadate catalysts for oxidation of 1-phenyl ethanol: from the discrete [V4O12]4− and [V10O28]6− anions to the anionic [V6O17]n4n− coordination polymer

Published:2018 Issue:40 Volume:20 Page:6273-6279
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Wang Ke¹²³⁴⁵,Xu Qiaofei¹²³⁴⁵,Ma Pengtao¹²³⁴⁵^ORCID,Zhang Chao¹²³⁴⁵^ORCID,Wang Jingping¹²³⁴⁵^ORCID,Niu Jingyang¹²³⁴⁵^ORCID

Affiliation:

1. Henan Key Laboratory of Polyoxometalate Chemistry

2. College of Chemistry and Chemical Engineering

3. Henan University

4. Kaifeng

5. P. R. China

Abstract

The hybrids assembled from {Ru(phen)₃} complexes and POV anions via electrostatic interactions have been systematically investigated, and we found that compounds 1 and 3 can be employed as efficient catalysts for the oxidation reaction of 1-phenyl ethanol to acetophenone.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CE/C8CE01237G

Reference44 articles.

1. Decavanadate: a journey in a search of a role

2. The Bioinorganic Chemistry of Vanadium

3. Polyoxometalates: Very Large ClustersNanoscale Magnets