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Concerning the mechanism of iodine(iii)-mediated oxidative dearomatization of phenols

  • Published:2018 Issue:13 Volume:16 Page:2324-2329
  • ISSN:1477-0520
  • Container-title:Organic & Biomolecular Chemistry
  • language:en
  • Short-container-title:Org. Biomol. Chem.

Author:

Harned Andrew M.1234ORCID

Affiliation:

1. Texas Tech University

2. Department of Chemistry & Biochemistry

3. Lubbock

4. USA

Abstract

DFT calculations were performed in order to investigate two mechanistic pathways for the iodine(iii)-mediated oxidative dearomatization of phenols.

Funder

Texas Tech University

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference57 articles.

1. Hypervalent Iodine Chemistry: Modern Developments in Organic Synthesis , ed. T. Wirth , Springer , Berlin , 2003

2. V. V. Zhdankin , Hypervalent Iodine Chemistry , Wiley , West Sussex , 2014

3. Two-electron phenolic oxidations using phenyliodonium dicarboxylates

4. Hypervalent iodine oxidation of p-alkoxyphenols and related compounds: a general route to p-benzoquinone monoacetals and spiro lactones

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