Unveiling the Mg(<scp>ii</scp>) promoted [3+2] cycloaddition reaction of mesitonitrile oxide to Baylis–Hilman adduct from the molecular electron density theory perspective-Reference-Cited by-同舟云学术

Unveiling the Mg(ii) promoted [3+2] cycloaddition reaction of mesitonitrile oxide to Baylis–Hilman adduct from the molecular electron density theory perspective

Published:2023 Issue:5 Volume:47 Page:2495-2506
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Domingo Luis R.¹^ORCID,Acharjee Nivedita²^ORCID

Affiliation:

1. Department of Organic Chemistry, University of Valencia, Dr Moliner 50, Burjassot, E-46100 Valencia, Spain

2. Department of Chemistry, Durgapur Government College, J. N. Avenue, Durgapur, West Bengal 713214, India

Abstract

The presence of Mg(ii) cation does not substantially accelerate this low polar zw-type [3+2] cycloaddition reaction, but changes the facial diastereoselectivity. These low polar reactions are completely ortho regioselective.

Funder

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/NJ/D2NJ05424H

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5. Reversal of stereoselectivity of Mg(II) catalysed 1,3-dipolar cycloaddition. Acceleration of cycloaddition by microwave irradiation

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