Incorporating polyoxometalates and organic ligands to pursue 3d–4f heterometallic clusters: a series of {Cr4Ln4} clusters stabilized by phthalic acid and [SiW12O40]4−-Reference-Cited by-同舟云学术

Incorporating polyoxometalates and organic ligands to pursue 3d–4f heterometallic clusters: a series of {Cr4Ln4} clusters stabilized by phthalic acid and [SiW12O40]4−

Published:2019 Issue:24 Volume:9 Page:13543-13549
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Gu Ya-Nan¹²³⁴⁵,Zhao Dan⁶⁷⁵,Yu Hao¹²³⁴⁵,Ge Rui¹²³⁴⁵,Li Zhong¹²³⁴⁵,Tian Chong-Bian⁸⁹¹⁰⁴⁵,Li Xin-Xiong¹²³⁴⁵^ORCID,Sun Yan-Qiong¹²³⁴⁵^ORCID,Zheng Shou-Tian¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Photocatalysis on Energy and Environment

2. College of Chemistry

3. Fuzhou University

4. Fuzhou

5. China

6. Fuqing Branch of Fujian Normal University

7. Fuqing

8. State Key Laboratory of Structural Chemistry

9. Fujian Institute of Research on the Structure of Matter

10. Chinese Academy of Sciences

Abstract

By introduction of trilacunary Keggin-type polyoxometalate to the hydrothermal reaction system of Cr³⁺, Ln³⁺ and phthalic acid, a series of novel {Cr₄Ln₄} heterometallic clusters have been obtained.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Fujian Province

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/RA/C9RA01731C

Reference54 articles.

1. Transformative 3d–4f coordination cluster carriers

2. Four 3d–4f heterometallic Ln45M7 clusters protected by mixed ligands