Chiroptical inversion of a planar chiral redox-switchable rotaxane-Reference-Cited by-同舟云学术

Chiroptical inversion of a planar chiral redox-switchable rotaxane

Published:2019 Issue:43 Volume:10 Page:10003-10009
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Gaedke Marius¹²³⁴,Witte Felix¹²³⁴,Anhäuser Jana⁵⁶⁷⁴,Hupatz Henrik¹²³⁴,Schröder Hendrik V.¹²³⁴^ORCID,Valkonen Arto⁸⁹¹⁰¹¹^ORCID,Rissanen Kari⁸⁹¹⁰¹¹^ORCID,Lützen Arne⁵⁶⁷⁴^ORCID,Paulus Beate¹²³⁴,Schalley Christoph A.¹²³⁴^ORCID

Affiliation:

1. Institut für Chemie und Biochemie

2. Freie Universität Berlin

3. 14195 Berlin

4. Germany

5. Kekulé-Institut für Organische Chemie und Biochemie

6. Universität Bonn

7. 53121 Bonn

8. University of Jyvaskyla

9. Department of Chemistry

10. 40014 Jyväskylä

11. Finland

Abstract

Reversible redox-switching of a planar chiral [2]rotaxane with a tetrathiafulvalene-bearing crown ether macrocycle generates a complete sign reversal of the main band in the ECD spectrum, as shown by experiment and rationalised by DFT calculations.

Funder

Alexander von Humboldt-Stiftung

Deutsche Forschungsgemeinschaft

Studienstiftung des Deutschen Volkes

Academy of Finland

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC03694F

Reference78 articles.