Mechanistic basis for tuning iridium hydride photochemistry from H2 evolution to hydride transfer hydrodechlorination-Reference-Cited by-同舟云学术

Mechanistic basis for tuning iridium hydride photochemistry from H2 evolution to hydride transfer hydrodechlorination

Published:2020 Issue:25 Volume:11 Page:6442-6449
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Barrett Seth M.¹²³⁴¹^ORCID,Stratakes Bethany M.¹²³⁴,Chambers Matthew B.¹²³⁴¹^ORCID,Kurtz Daniel A.¹²³⁴^ORCID,Pitman Catherine L.¹²³⁴^ORCID,Dempsey Jillian L.¹²³⁴^ORCID,Miller Alexander J. M.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of North Carolina at Chapel Hill

3. Chapel Hill

4. USA

Abstract

The innate H₂ evolution photochemistry of an iridium hydride complex is diverted towards photochemical hydrodechlorination of dichloromethane with high selectivity and quantum yield.

Funder

Division of Graduate Education

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC00422G

Reference66 articles.

1. Highly Efficient OLEDs with Phosphorescent Materials , ed. H. Yersin , Wiley-VCH , Weinheim, Germany , 2008

2. Iridium(III) in Optoelectronic and Photonics Applications , ed. E. Zysman-Colman , John Wiley & Sons , Chichester, UK , 2017