Diversion of the Arbuzov reaction: alkylation of C–Cl instead of phosphonic ester formation on the fullerene cage-Reference-Cited by-同舟云学术

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Diversion of the Arbuzov reaction: alkylation of C–Cl instead of phosphonic ester formation on the fullerene cage

Published:2019 Issue:30 Volume:17 Page:7155-7160
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Kraevaya Ol'ga A.¹²³⁴⁵,Peregudov Alexander S.⁶²³,Troyanov Sergey I.⁷⁸²³^ORCID,Godovikov Ivan⁶²³,Fedorova Natalya E.⁹²³^ORCID,Klimova Regina R.⁹²³^ORCID,Sergeeva Vasilina A.¹⁰²³,Kameneva Larisa V.¹⁰²³,Ershova Elizaveta S.¹⁰²³,Martynenko Vyacheslav M.⁴⁵¹¹³,Claes Sandra¹²¹³¹⁴¹⁵,Kushch Alla A.⁹²³^ORCID,Kostyuk Svetlana V.¹⁰²³,Schols Dominique¹²¹³¹⁴¹⁵,Shestakov Alexander F.⁴⁵¹¹³¹⁶,Troshin Pavel A.¹²³⁴⁵^ORCID

Affiliation:

1. Skolkovo Institute of Science and Technology

2. Moscow

3. Russia

4. IPCP RAS

5. Semenov Prospect 1

6. INEOS RAS

7. Department of Chemistry

8. Moscow Lomonosov State University

9. Honored Academician N.F.Gamaleya National Research Centre for Epidemiology and Microbiology of the Ministry of Health of the Russian Federation

10. Research Centre for Medical Genetics RAMS

11. Chernogolovka

12. Rega Institute for Medical Research

13. KU Leuven

14. Leuven

15. Belgium

16. Faculty of Fundamental Physics & Chemical Engineering

Abstract

We report an “inversed” Arbuzov reaction of C₆₀Ar₅Cl with P(OR)₃ producing C₆₀Ar₅R with an excellent selectivity.

Funder

Ministry of Education and Science of the Russian Federation

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/OB/C9OB00593E

Reference43 articles.

1. Fullerenes for Applications in Biology and Medicine

2. Fullerene Sugar Balls: A New Class of Biologically Active Fullerene Derivatives

3. Giant Glycosidase Inhibitors: First- and Second-Generation Fullerodendrimers with a Dense Iminosugar Shell

4. Carbon nanostructures in biology and medicine

5. Review: Fullerene based acceptors for efficient bulk heterojunction organic solar cell applications

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4. Effect of Water-Soluble Chlorine-Containing Buckminsterfullerene Derivative on the Metabolism of Reactive Oxygen Species in Human Embryonic Lung Fibroblasts;Oxygen;2022-12-27

5. THE EFFECT OF WATER-SOLUBLE DERIVATIVES OF FULLENE C60 ON THE LEVEL OF OXIDATIVE STRESS AND ON THE TRANSCRIPTIONAL ACTIVITY OF GENES REGULATING PRO- AND ANTIOXIDANT ACTIVITY OF HUMAN EMBRYONIC FIBROBLAST CELLS (HELFs) IN VITRO;Russian Journal of Biological Physics and Chemisrty;2022-11-15

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