Non-stabilized enolates – versatile nucleophiles in transition metal-catalysed allylic alkylations

Author:

Kazmaier Uli1234

Affiliation:

1. Institute of Organic Chemistry

2. Saarland University

3. 66041 Saarbrücken

4. Germany

Abstract

This review covers new developments in the transition metal-catalyzed allylic alkylations of non-stabilized enolates, preferentially generated from ketone, esters or amides.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Reference194 articles.

1. Asymmetric Transition-Metal-Catalyzed Allylic Alkylations:  Applications in Total Synthesis

2. Metallkatalysierte enantioselektive Allylierungen in der asymmetrischen Synthese

3. G. Helmchen , U.Kazmaier and S.Förster, in Catalytic Asymmetric Synthesis, ed. I. Ojima, Wiley-VCH, Weinheim, 2010, pp. 497–641

4. Topics in Organometallic Chemistry – Transition Metal Catalyzed Enantioselective Allylic Substitution in Organic Synthesis, ed. U. Kazmaier, Springer, Heidelberg, 2011

5. A. Bayer and U.Kazmaier, in Metal-Catalyzed Cross-Coupling Reactions and More, ed. A. De Meijere, S. Bräse and M. Oestreich, Wiley-VCH, Weinheim, 2014, pp. 926–994, and references cited therein

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