Selective recognition and enrichment of C<sub>70</sub> over C<sub>60</sub> using an anthracene-based nanotube-Reference-Cited by-同舟云学术

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Selective recognition and enrichment of C₇₀ over C₆₀ using an anthracene-based nanotube

Published:2024 Issue:26 Volume:15 Page:10214-10220
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Nian Hao¹²,Wang Song-Meng¹,Wang Yan-Fang¹,Zheng Yu-Tao¹,Zheng Li-Shuo¹,Wang Xiaoping¹,Yang Liu-Pan³^ORCID,Jiang Wei¹^ORCID,Cao Liping²^ORCID

Affiliation:

1. Department of Chemistry, Southern University of Science and Technology, Xueyuan Blvd 1088, Shenzhen, 518055, China

2. College of Chemistry and Materials Science, Northwest University, Xi'an, 710069, P. R. China

3. School of Pharmaceutical Science, University of South China, Hengyang, Hunan, 421001, China

Abstract

A hexagonal anthracene-based nanotube (1) was synthesized through a one-pot Suzuki–Miyaura cross-coupling reaction. 1 shows high binding affinity and selectivity to C70 over C60 in toluene, resulting in enrichment of C70.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC02814G

Reference48 articles.

1. Solid C60: a new form of carbon

2. Supramolecular fullerene chemistry

3. T.Kawase , in Supramolecular Chemistry of Fullerenes and Carbon Nanotubes , ed. N. Martín and J.-F. Nierengarten , Wiley-VCH , Weinheim, Germany , 2012 , ch. 3, pp. 55–78

4. C60embedded in γ-cyclodextrin: a water-soluble fullerene

5. An Inclusion Complex of C60with Organosilylated γ-Cyclodextrin: Drastic Enhancement of Apparent Solubility of C60in Nonpolar and Weakly Polar Organic Solvents

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