A metal–organic framework based on a custom-designed diisophthalate ligand exhibiting excellent hydrostability and highly selective adsorption of C2H2 and CO2 over CH4
Author:
Affiliation:
1. Key Laboratory of the Ministry of Education for Advanced Catalysis Materials
2. College of Chemistry and Life Sciences
3. Zhejiang Normal University
4. Jinhua 321004
5. China
Abstract
The ligand truncation strategy was employed to devise a novel bent diisophthalate ligand which was used to construct a copper-based MOF exhibiting highly selective C2H2/CH4 and CO2/CH4 separations.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Zhejiang Province
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT00863A
Reference96 articles.
1. Efficient CO 2 Removal for Ultra ‐ Pure CO Production by Two Hybrid Ultramicroporous Materials
2. Microporous Cobalt(II)–Organic Framework with Open O-Donor Sites for Effective C2H2 Storage and C2H2/CO2 Separation at Room Temperature
3. Controlling guest conformation for efficient purification of butadiene
4. Gas/vapour separation using ultra-microporous metal–organic frameworks: insights into the structure/separation relationship
5. Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene
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