Contrasted behaviours of methylthiolated perylene and pyrene as organic semiconductors: implications of molecular electronic structure and crystal structure

Author:

Takimiya Kazuo123ORCID,Bulgarevich Kirill1ORCID,Horiuchi Singo12

Affiliation:

1. Emergent Molecular Function Research Team, RIKEN Center for Emergent Matter Science (CEMS), 2-1 Hirosawa, Wako, Saitama 351-0198, Japan

2. Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aoba, Aramaki, Aoba-ku, Sendai, Miyagi 980-8578, Japan

3. Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, Miyagi 980-8577, Japan

Abstract

Prompted by 1,3,6,8-tetrakis(methylthio)pyrene (MT-pyrene) showing the ultrahigh mobility in its single-crystal transistors, we have synthesized and characterized its closely related compound, 2,5,8,11-tetrakis(methylthio)perylene (MT-perylene).

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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