Polymer conformation determination by NMR spectroscopy: comparative diffusion ordered 1H-NMR spectroscopy of poly(2-ethyl-2-oxazoline)s and poly(ethylene glycol) in D2O

Author:

Monnery Bryn D.12ORCID,Jerca Valentin Victor3ORCID,Hoogenboom Richard1ORCID,Swift Thomas4ORCID

Affiliation:

1. Supramolecular Chemistry Group, Centre of Macromolecular Chemistry (CMaC), Department of Organic and Macromolecular Chemistry, Ghent University, Krijgslaan 281 S4, B-9000 Ghent, Belgium

2. Department of Biomedical Engineering, University Medical Centre Groningen, University of Groningen, Ant. Deusinglaan 1, 9713 AV Groningen, The Netherlands

3. Smart Organic Materials Group, “Costin D. Nenitzescu” Institute of Organic and Supramolecular Chemistry, Romanian Academy, 202B Splaiul Independentei, 060023 Bucharest, Romania

4. Polymer and Biomaterials Chemistry Laboratories, University of Bradford, Bradford, West Yorkshire BD 7 1DP, UK

Abstract

Diffusion ordered 1H-NMR spectroscopy (DOSY) is a useful, non-destructive technique for analysing polymer hydrodynamic size and in solution viscosity.

Funder

Royal Society of Chemistry

Universiteit Gent

Publisher

Royal Society of Chemistry (RSC)

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