Rational regulation of acetylene adsorption and separation for ultra-microporous copper-1,2,4-triazolate frameworks by halogen hydrogen bonds-Reference-Cited by-同舟云学术

Rational regulation of acetylene adsorption and separation for ultra-microporous copper-1,2,4-triazolate frameworks by halogen hydrogen bonds

Published:2022 Issue:48 Volume:14 Page:18200-18208
ISSN:2040-3364
Container-title:Nanoscale
language:en
Short-container-title:Nanoscale

Author:

Li Hai-Peng¹,Dou Zhao-Di¹,Xiao Yi¹,Fan Guan-Jiang¹,Pan Dong-Chen¹,Hu Man-Cheng¹,Zhai Quan-Guo¹^ORCID

Affiliation:

1. Key Laboratory of Macromolecular Science of Shaanxi Province, School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an, Shaanxi, 710062, China

Abstract

A series of ultra-microporous copper(i)-1,2,4-triazolate frameworks exhibit moderate C2H2 uptake capacity, high C2H2/CO2 and C2H2/C2H4 separation ability, and remarkably lower isosteric heat of C2H2 adsorption regulated by halogen hydrogen bond.

Funder

Fundamental Research Funds for the Central Universities

Natural Science Foundation of Shaanxi Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NR/D2NR04187A

Reference60 articles.

1. Gas/vapour separation using ultra-microporous metal–organic frameworks: insights into the structure/separation relationship