Hydrogen evolution driven by heteroatoms of bidentate N-heterocyclic ligands in iron(ii) complexes

Author:

Keszei Soma12ORCID,Wang Yiqing3,Zhou Haotian3,Ollár Tamás2ORCID,Kováts Éva4,Frey Krisztina2,Tapasztó Levente1,Shen Shaohua3ORCID,Pap József Sándor2ORCID

Affiliation:

1. Centre for Energy Research, Institute of Technical Physics and Materials Science, H-1121, Konkoly-Thege út 29-33, Budapest, Hungary

2. Centre for Energy Research, Surface Chemistry and Catalysis Department, H-1121, Konkoly-Thege út 29-33, Budapest, Hungary

3. International Research Center for Renewable Energy (IRCRE), State Key Laboratory of Multiphase Flow in Power Engineering (MFPE), Xi'an Jiaotong University, Xi'an, Shaanxi 710049, China

4. Institute for Solid State Physics and Optics, Wigner Research Centre for Physics, P.O. Box 49, H-1525 Budapest, Hungary

Abstract

Non-coordinated heteroatoms in non-symmetrical bidentate N-heterocyclic ligands modulate the reactivity of Fe(ii) complexes towards acids under reductive conditions.

Funder

Nemzeti Kutatási Fejlesztési és Innovációs Hivatal

Publisher

Royal Society of Chemistry (RSC)

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