Playing with the cavity size of exTTF-based self-assembled cages

Author:

Dekhtiarenko Maksym12ORCID,Szalóki György1ORCID,Croué Vincent1,Bou Zeid Jennifer1,Canevet David1ORCID,Allain Magali1ORCID,Carré Vincent3ORCID,Aubriet Frédéric3ORCID,Voitenko Zoia2ORCID,Sallé Marc1ORCID,Goeb Sébastien1ORCID

Affiliation:

1. Univ Angers, CNRS, MOLTECH-Anjou, F-49000 Angers, France

2. Taras Shevchenko National University of Kyiv, 64/13 Volodymyrska st., Kyiv 01033, Ukraine

3. Université de Lorraine, LCP-A2MC, F-57000 Metz, FranceLCP

Abstract

The binding properties of electron-rich M4L2 metallacages with different cavity sizes, constructed through coordination-driven self-assembly of extended tetrathiafulvalene (exTTF)-based ligands, are evaluated and show a high size selectivity for different guest molecules.

Funder

Universite Angers

Agence Nationale de la Recherche

Campus France

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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