Reversibly photoswitchable catalysts for high regioselectivity and enantioselectivity in polymerization of allenes

Author:

Zhou Li1ORCID,Wu Yong-Jie1,Chen Kun1,Zhou Xing-Yu1,Zou Hui1ORCID,Kang Shu-Ming2,Liu Na3,Wu Zong-Quan4ORCID

Affiliation:

1. Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, and Anhui Key Laboratory of Advanced Catalytic Materials and Reaction Engineering, Hefei University of Technology, Hefei 230009, Anhui Province, China

2. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

3. The School of Pharmaceutical Sciences, Jilin University, Changchun 130021, Jilin Province, China

4. State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, Jilin Province, China

Abstract

Two enantiomers Ni(ii)/LR-azo and Ni(ii)/LS-azo could be used as reversible photo-switchable catalysts for the high regioselectivity and enantioselectivity polymerization of allene monomers.

Funder

Fundamental Research Funds for the Central Universities

Natural Science Foundation of Anhui Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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