Pressure-induced order–disorder transitions in β-In2S3: an experimental and theoretical study of structural and vibrational properties

Author:

Gallego-Parra Samuel1ORCID,Gomis Óscar2ORCID,Vilaplana Rosario2ORCID,Cuenca-Gotor Vanesa Paula1ORCID,Martínez-García Domingo3,Rodríguez-Hernández Plácida4ORCID,Muñoz Alfonso4ORCID,Romero Aldo5,Majumdar Arnab67ORCID,Ahuja Rajeev68ORCID,Popescu Catalin9ORCID,Manjón Francisco Javier1ORCID

Affiliation:

1. Instituto de Diseño para la Fabricación y Producción Automatizada, MALTA Consolider Team, Universitat Politècnica de València, 46022 València, Spain

2. Centro de Tecnologías Físicas, MALTA Consolider Team, Universitat Politècnica de València, 46022 València, Spain

3. Departamento de Física Aplicada-ICMUV-MALTA Consolider Team, Universitat de València, c/Dr. Moliner 50, 46100 Burjassot (València), Spain

4. Departamento de Física, Instituto de Materiales y Nanotecnología, MALTA Consolider Team, Universidad de La Laguna, 38207 San Cristóbal de La Laguna, Spain

5. Physics Department, West Virginia University, Morgantown, 26505, USA

6. Department of Physics and Astronomy, Uppsala University, Box 516, Uppsala, SE-75120, Sweden

7. Département de Physique and Regroupement Québécois sur les Matériaux de Pointe, Université de Montréal, C. P. 6128, Succursale Centre-Ville, Montréal, Québec H3C 3J7, Canada

8. Department of Physics, Indian Institute of Technology Ropar, Rupnagar 140001, Punjab, India

9. ALBA-CELLS, MALTA Consolider Team, 08290 Cerdanyola del Valles (Barcelona), Catalonia, Spain

Abstract

This joint experimental and theoretical study of the structural and vibrational properties of β-In2S3 upon compression shows that this tetragonal defect spinel undergoes two reversible pressure-induced order–disorder transitions up to 20 GPa.

Funder

Generalitat Valenciana

National Science Foundation

Abraham Lincoln Brigade Archives

Carl Tryggers Stiftelse för Vetenskaplig Forskning

Vetenskapsrådet

Agencia Estatal de Investigación

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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