A general route to sulfones via insertion of sulfur dioxide promoted by cobalt oxide-Reference-Cited by-同舟云学术

A general route to sulfones via insertion of sulfur dioxide promoted by cobalt oxide

Published:2016 Issue:8 Volume:3 Page:985-988
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zheng Danqing¹²³⁴,Chen Mo⁵²⁶⁴,Yao Liangqing⁵²⁶⁴,Wu Jie¹²³⁴⁷

Affiliation:

1. Department of Chemistry

2. Fudan University

3. Shanghai 200433

4. China

5. Obstetrics and Gynecology Hospital

6. Shanghai 200011

7. State Key Laboratory of Organometallic Chemistry

Abstract

A cobalt-promoted coupling reaction of triethoxysilanes, sulfur dioxide, and electrophiles is developed. Different electrophilic partners including alkyl bromides, iodonium salts, and electron-poor (hetero)aryl chlorides work well under the standard conditions.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/QO/C6QO00099A

Reference60 articles.

1. S. D. Burke , in Encyclopedia of Reagents for Organic Synthesis, ed. L. A. Paquette, Wiley, Chichester, 1995, vol. 7, p. 4688

2. New Organic Chemistry of Sulfur Dioxide

3. Ullmann's Encyclopedia of Industrial Chemistry, ed. B. Elvers, S. Hawkins and W. Russey, VCH, Weinheim, Germany, 5th edn, 1994, vol. A25

4. Fixation of sulfur dioxide into small molecules

Cited by 81 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Palladium-Catalyzed Reductive Cross-Coupling of Propargyl Acetates with Aryl Iodides Involving the Insertion of SO₂;Chinese Journal of Organic Chemistry;2024

2. Palladium-catalyzed domino cyclization/direct functionalization involving the insertion of SO₂;New Journal of Chemistry;2024

3. Ni-Catalyzed Hydrosulfonylation of Alkenes with Aromatic Iodides and K₂S₂O₅;Organic Letters;2023-10-30

4. A Redox‐neutral Nickel‐catalysed Sulfonylation of (Hetero)aryl Boronic Acids with 2‐Chlorothiazoles;Chemistry – An Asian Journal;2023-10-26

5. Oxidative Cascade Sulfonylation/Cyclisation of N‐Propargylindoles with Hantzsch Esters via Sulfur Dioxide Insertion;Advanced Synthesis & Catalysis;2023-06-06