Boosting the electrocatalytic activity of 2D ultrathin BiOX/rGO (X = F, Cl, Br, and I) nanosheets as sulfur hosts: insight into the electronegativity effect of halogenated elements on the electrochemical performances of lithium–sulfur batteries

Author:

Wang Meili1,Han Yumiao2,Peng Huaiqi1,Jin Ziqian1,Guan Hui2,Ma Shiyu3,Li Xin1,Ren Yunlai1ORCID,Xie Lixia1,Zheng Xianfu1,Zhang Jianmin2ORCID,Dong Yutao14ORCID

Affiliation:

1. College of Science, Henan Agricultural University, Zhengzhou 450002, China

2. College of Chemistry, Zhengzhou University, Zhengzhou 450001, China

3. School of Chemical and Printing-Dyeing Engineering, Henan University of Engineering, Zhengzhou 450007, China

4. Longzihu New Energy Laboratory, Zhengzhou Institute of Emerging Industrial Technology, Henan University, Zhengzhou 450000, China

Abstract

Ultrathin BiOX/rGO (X = F, Cl, Br, and I) nanosheets serve as novel sulfur hosts in Li–S batteries. The influence of X on the electrochemical performance and redox mechanism is elucidated through in situ Raman/XRD characterization and DFT analysis.

Funder

Henan Agricultural University

National Natural Science Foundation of China

Science and Technology Department of Henan Province

Publisher

Royal Society of Chemistry (RSC)

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