Supramolecular chirality in the crystals of mononuclear and polymeric cobalt(ii) complexes with enantiopure and racemic N-thiophosphorylated thioureas

Author:

Kataeva Olga12345ORCID,Metlushka Kirill12345ORCID,Ivshin Kamil12345,Yamaleeva Zilya12345,Zinnatullin Ruzal12345,Nikitina Kristina12345,Badeeva Elena12345,Khrizanforova Vera12345ORCID,Budnikova Yulia12345ORCID,Naumann Marco678,Wellm Christoph678910ORCID,Alfonsov Alexey678,Kataev Vladislav678,Büchner Bernd678910,Knupfer Martin678

Affiliation:

1. A. E. Arbuzov Institute of Organic and Physical Chemistry

2. FRC Kazan Scientific Center

3. Russian Academy of Sciences

4. 420088 Kazan

5. Russia

6. Leibniz IFW Dresden

7. D-01069 Dresden

8. Germany

9. Institute for Solid State and Materials Physics

10. TU Dresden

Abstract

The control of stereochemistry in Co(ii) complexes was provided by additional pyridine and pyrazine ligands. 1D and 2D supramolecular homochiral arrangements in racemic crystals of mononuclear complexes are transferred to their polymeric counterparts.

Funder

Deutsche Forschungsgemeinschaft

Russian Foundation for Basic Research

Kazan Federal University

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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