Metal-free visible light photoredox enables generation of carbyne equivalents via phosphonium ylide C–H activation
Author:
Affiliation:
1. Division of Chemistry and Biological Chemistry
2. School of Physical and Mathematical Sciences
3. Nanyang Technological University
4. Singapore 637371
Abstract
Phosphonium ylides have shown their synthetic usefulness in important carbon–carbon bond formation processes. Our new strategy employs phosphonium ylides as novel carbyne equivalents and features a new approach for constructing carbon–carbon bonds from alkenes.
Funder
National Research Foundation Singapore
Ministry of Education – Singapore
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/SC/C8SC04195D
Reference45 articles.
1. Formation and reactions of monovalent carbon intermediates. I. Photolysis of diethyl mercuribisdiazoacetate
2. Formation and reactions of monovalent carbon intermediates. II. Further studies on the decomposition of diethyl mercurybisdiazoacetate
3. Formation and reactions of monovalent carbon intermediates. III. Reaction of carbethoxymethyne with olefins
4. Generating carbyne equivalents with photoredox catalysis
5. Visible Light-Mediated Atom Transfer Radical Addition via Oxidative and Reductive Quenching of Photocatalysts
Cited by 26 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Design of Organic Radical Cations as Potent Hydrogen‐Atom Transfer Catalysts for C−H Functionalization;Asian Journal of Organic Chemistry;2024-01-08
2. General Synthesis of N-Alkylindoles from N,N-Dialkylanilines via [4 + 1] Annulative Double C–H Functionalization;Journal of the American Chemical Society;2023-11-29
3. Rh(III)-Catalyzed Synthesis of Isocoumarins via C–H Activation of Phenacyl Phosphoniums with Iodonium Ylides;Synthesis;2023-11-23
4. Bidirectional Elongation Strategy Using Ambiphilic Radical Linchpin for Modular Access to 1,4-Dicarbonyls via Sequential Photocatalysis;Journal of the American Chemical Society;2023-07-25
5. From‐Neutral‐to‐Neutral Reductive Radical Coupling of Non‐Activated Alcohols and Styrenes;ChemistryEurope;2023-07-19
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3