Crystallization kinetics of amorphous red phosphorus to black phosphorus by chemical vapor transport

Author:

Zhang Shuai12,Ma Shufang1ORCID,Hao Xiaodong1ORCID,Liu Qingming12,Hou Yanyan12,Kong Qingbo12,Chen Zhaoru2,Ma Hanyu2,Xi Ting12,Xu Yang12,Cao Ben12,Shang Lin1,Han Bin1,Xu Bingshe13

Affiliation:

1. Materials Institute of Atomic and Molecular Science, Shaanxi University of Science and Technology, Xi'an 710021, China

2. School of Materials Science and Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China

3. Key Laboratory of Interface Science and Engineering in Advanced Materials of Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, China

Abstract

The aRP–P4-HP–BP three-stage phase transition revealed the crystallization kinetics and nucleation mechanism of the high-quality BP crystal synthesized by the CVT reaction in the aRP–Sn–I system.

Funder

National Natural Science Foundation of China

Shanxi Provincial Key Research and Development Project

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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