From propenolysis to enyne metathesis: tools for expedited assembly of 4<i>a</i>,8<i>a</i>-azaboranaphthalene and extended polycycles with embedded BN-Reference-Cited by-同舟云学术

From propenolysis to enyne metathesis: tools for expedited assembly of 4a,8a-azaboranaphthalene and extended polycycles with embedded BN

Published:2024 Issue:15 Volume:15 Page:5674-5680
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Rulli Federica¹^ORCID,Sanz-Liarte Guillem²^ORCID,Roca Pol²,Martínez Nina¹,Medina Víctor²,Puig de la Bellacasa Raimon¹^ORCID,Shafir Alexandr²³^ORCID,Cuenca Ana B.¹³^ORCID

Affiliation:

1. BISi-Bonds/CRISOL Group, Dept. of Organic and Pharmaceutical Chemistry. Institut Químic de Sarrià, Universitat Ramon Llull, Vía Augusta 390, 08017 Barcelona, Spain

2. BISi-Bonds Group, Dept. Química Biológica. Institut de Química Avançada de Catalunya, IQAC-CSIC, C/Jordi Girona 20, 08034 Barcelona, Spain

3. Centro de Innovación en Química Avanzada (ORFEO-CINQA), Barcelona, Spain

Abstract

A new integrated approach to BN-polycycles is rooted in a clean condensation of amines with B(allyl)3. The end game includes a gram-scale synthesis of BN-naphthalene through efficient aromatization, or assembly of BN-polycycles via enyne metathesis.

Funder

Agència de Gestió d'Ajuts Universitaris i de Recerca

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC06676B

Reference51 articles.

1. B-N as a C-C substitute in aromatic systems

2. Recent Advances in Azaborine Chemistry

3. 624. New heteroaromatic compounds. Part I. 9-Aza-10-boraphenanthrene

4. New heteroaromatic compounds. XXVI. Synthesis of borazarenes

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